化学传感器：仿真与建模 第5卷 电化学传感器 上 英文影印版2025|PDF|Epub|mobi|kindle电子书版本百度云盘下载

化学传感器：仿真与建模 第5卷 电化学传感器 上 英文影印版PDF格式电子书版下载

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PART 1:SOLID-STATE ELECTROCHEMICAL SENSORS3

1 SURFACE AND INTERFACE DEFECTS IN IONIC CRYSTALS&N.F.Uvarov3

1 Introduction3

1.1 Solid Electrolytes and Electrodes for Electrochemical Sensors:A Brief Overview3

1.2 Surface and Interface Properties of Ionic Solids6

2 Calculation of the Surface Potential and Surface Defects Using the Stern Model8

2.1 Description of the Model8

2.2 Pure Crystals of the NaCl Type10

2.3 Surface Potential in NaCl Crystals Containing Divalent Cations13

2.4 Comparison with Experimental Data15

2.5 Surface Potential and Concentration of Point Defects on Grain Boundaries of Superionic Oxide Ceramics15

2.6 Surface Disorder in Terms of Energy Diagrams23

2.7 Defects on Interfaces25

3 Size Effects in Nanocomposite Solid Electrolytes29

4 Applications in Sensors30

5 Conclusions34

References34

2 SOLID-STATE ELECTROCHEMICAL GAS SENSORS&C.O.Park I.Lee D.R.Lee J.W.Fergus N.Miura H.J.Yoo41

1 Introduction41

2 Electrode Potentials42

3 Types of Electrochemical Sensors46

3.1 Equilibrium Potentiometric Sensors46

3.2 Mixed Potentiometric Sensors49

3.3 Amperometric Sensors53

4 Applications57

4.1 Oxygen Sensors57

4.2 Carbon Dioxide Sensors64

4.3 NOx Sensors66

4.4 SOx Sensors76

4.5 Hydrogen Sensors77

Acknowledgments86

References86

PART 2:ELECTROCHEMICAL SENSORS FOR LIQUID ENVIRONMENTS95

3 MODELING AND SIMULATION OF IONIC TRANSPORT PROCESSES THROUGH IDEAL ION-EXCHANGE MEMBRANE SYSTEMS&A.A.Moya95

1 Introduction95

2 Theoretical Description98

2.1 Ionic Transport in Ideal Ion-Exchange Membrane Systems98

2.2 Electric Current Perturbations101

2.3 Analytical Solutions102

3 The Network Model106

4 Network Simulation108

4.1 Transient Response109

4.2 Electrochemical Impedance113

5 Conclusion121

Nomenclature122

Appendix123

Acknowledgments124

References124

4 MECHANISM OF POTENTIAL DEVELOPMENT FOR POTENTIOMETRIC SENSORS,BASED ON MODELING OF INTERACTION BETWEEN ELECTROCHEMICALLY ACTIVE COMPOUNDS FROM THE MEMBRANE AND ANALYTE&R.-I.Stefan-van Staden131

1 Introduction131

2 The Membrane-Solution Interface132

3 Membrane Configuration132

4 New Theoretical Model for Potential Development Based on Membrane Equilibria133

5 Mechanism of the Potential Development134

6 Modeling—A Theoretical Approach to Predict the Response and Mechanism of Potential Development137

7 Selectivity of Potentiometric Sensors:Explanation through Membrane Equilibria149

7.1 Influence of the Composition of the Membrane on the Selectivity of Potentiometric Sensors150

8 Conclusions151

References152

5 COMPUTER MODELING OF THE POTENTIOMETRIC RESPONSE OF ION-SELECTIVE ELECTRODES WITH IONOPHORE-BASED MEMBRANES&K.N.Mikhelson155

1 Introduction155

2 Physical Models of Ionophore-Based Membranes158

2.1 Levels of ISE Membrane Modeling158

2.2 One-Dimensional Approach to ISE Membrane Modeling160

2.3 Segmented Model of the ISE Membrane161

2.4 Integral Model of the ISE Membrane164

3 Computer Modeling for the Phase Boundary Theory166

3.1 Description of the ISE Response in Mixed Solutions Containing Differently Charged Ions166

3.2 Description of Apparently Non-Nernstian Response Slopes of Ion-Selective Electrodes168

4 Modeling Using the Multispecies Approximation170

4.1 The Essence of the Multispecies Approximation170

4.2 System of Equations for Implementation of the Multispecies Model171

4.3 Selected Results of Modeling Using the Multispecies Approximation174

5 Diffusion Layer Model:Example of Local Equilibrium Modeling179

6 Advanced Nonequilibrium Modeling in Real Time and Space181

7 Conclusions194

Acknowledgments194

References195

6 MODELS OF RESPONSE IN MIXED-ION SOLUTIONS FOR ION-SENsITIVE FIELD-EFFECT TRANSISTORS&Sergio Bermejo201

1 Introduction201

2 ISFET Basics202

2.1 Principles of Electrochemical Operation202

2.2 Structures and Materials206

3 Electrochemical Models211

3.1 The Metal-Solution Junction211

3.2 The Oxide--Solution Junction219

3.3 Membrane-Based ISFETs225

3.4 A General Approach for ISFET Modeling in Mixed-Ion Solutions232

4 Conclusions242

Appendix:SPICE Models242

References243