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Alder ene reaction1

Aldol condensation3

Algar-Flynn-Oyamada reaction5

Allan-Robinson reaction8

Appel reaction10

Arndt-Eistert homologation12

Baeyer-Villiger oxidation14

Baker-Venkataraman rearrangement16

Bamberger rearrangement18

Bamford-Stevens reaction20

Barbier coupling reaction22

Bargellini reaction24

Bartoli indole synthesis26

Barton radical decarboxylation28

Barton-McCombie deoxygenation30

Barton nitrite photolysis32

Barton-Zard reaction34

Batcho-Leimgruber indole synthesis36

Baylis-Hillman reaction39

Beckmann rearrangement41

Beirut reaction43

Benzilic acid rearrangement45

Benzoin condensation47

Bergman cyclization49

Biginelli pyrimidone synthesis51

Birch reduction53

Bischler-M？hlau indole synthesis55

Bischler-Napieralski reaction57

Blaise reaction59

Blanc chloromethylation61

Blum aziridine synthesis63

Boekelheide reaction65

Boger pyridine synthesis67

Borch reductive amination69

Borsche-Drechsel cyclization71

Boulton-Katritzky rearrangement73

Bouveault aldehyde synthesis75

Bouveault-Blanc reduction77

Boyland-Sims oxidation79

Bradsher reaction81

Brook rearrangement83

Brown hydroboration85

Bucherer carbazole synthesis87

Bucherer reaction90

Bucherer-Bergs reaction92

Büchner-Curtius-Schlotterbeck reaction94

Büchner method of ring expansion96

Buchwald-Hartwig C-N bond and C-O bond formation reactions98

Burgess dehydrating reagent100

Cadiot-Chodkiewicz coupling102

Camps quinolinol synthesis104

Cannizzaro dispropotionation107

Carroll rearrangement109

Castro-Stephens coupling112

Chan alkyne reduction114

Chan-Lam coupling reaction116

Chapman rearrangement118

Chichibabin pyridine synthesis120

Chugaev reaction123

Ciamician-Dennsted rearrangement125

Claisen condensation127

Claisen isoxazole synthesis129

Claisen rearrangement131

Abnormal Claisen rearrangement133

Eschenmoser-Claisen amide acetal rearrangement135

Ireland-Claisen(silyl ketene acetal)rearrangement137

Johnson-Claisen(orthoester)rearrangement139

Clemmensen reduction141

Combes quinoline synthesis144

Conrad-Limpach reaction147

Cope elimination reaction149

Cope rearrangement151

Oxy-Cope rearrangement152

Anionic oxy-Cope rearrangement153

Corey-Bakshi-Shibata(CBS)reduction154

Corey-Chaykovsky reaction157

Corey-Fuchs reaction160

Corey-Kim oxidation162

Corey-Nicolaou macrolactonization164

Corey-Seebach dithiane reaction166

Corey-Winter olefin synthesis168

Cfiegee glycol cleavage171

Criegee mechanism of ozonolysis173

Curtius rearrangement175

Dakin oxidation177

Dakin-West reaction179

Danheiser annulation181

Darzens glycidic ester condensation183

Davis chiral oxaziridine reagent185

Delépine amine synthesis187

de Mayo reaction189

Demjanov rearrangement191

Tiffeneau-Demjanov rearrangement193

Dess-Martin oxidation195

Dieckmann condensation197

Diels-Alder reaction199

Dienone-phenol rearrangement202

Di-π-methane rearrangement204

Doebner quinoline synthesis206

D？tz reaction208

Dowd-Beckwith ring expansion210

Erlenmeyer-Pl？chl azlactone synthesis212

Eschenmoser-Tanabe fragmentation214

Eschweiler-Clarke reductive alkylation of amines216

Evans aldol reaction218

Favorskii rearrangement and quasi-Favorskii rearrangement220

Feist-Bénary furan synthesis222

Ferrier carbocyclization224

Ferrier glycal allylic rearrangement227

Fiesselmann thiophene synthesis230

Fischer indole synthesis233

Fischer oxazole synthesis235

Fleming-Tamao oxidation237

Tamao-Kumada oxidation239

Friedel-Crafts reaction240

Ffiedl？nder quinoline synthesis243

Fries rearrangement245

Fukuyama amine synthesis247

Fukuyama reduction249

Gabriel synthesis251

Ing-Manske procedure253

Gabriel-Colman rearrangement255

Gassman indole synthesis257

Gattermann-Koch reaction259

Gewald aminothiophene synthesis261

Glaser coupling263

Eglinton coupling265

Gomberg-Bachmann reaction267

Gould-Jacobs reaction269

Grignard reaction271

Grob fragmentation273

Guareschi-Thorpe condensation275

Hajos-Wiechert reaction277

Haller-Bauer reaction279

Hantzsch dihydropyridine synthesis281

Hantzsch pyrrole synthesis283

Heck reaction285

Heteroaryl Heck reaction287

Hegedus indole synthesis289

Hell-Volhard-Zelinsky reaction291

Henry nitroaldol reaction293

Hinsberg synthesis of thiophene deritvatives295

Hiyama cross-coupling reaction297

Hiyama-Denmark cross-coupling reaction299

Hofmann rearrangement302

Hofmann-L？ffler-Freytag reaction304

Horner-Wadsworth-Emmons reaction306

Houben-Hoesch synthesis308

Hunsdiecker-Borodin reaction310

Hurd-Mori 1,2,3-thiadiazole synthesis312

Jacobsen-Katsuki epoxidation314

Japp-Klingemann hydrazone synthesis316

Jones oxidation318

Julia-Kocienski olefination321

Julia-Lythgoe olefination323

Kahne-Crich glycosidation325

Keck macrolactonization327

Knoevenagel condensation329

Knorr pyrazole synthesis331

Paal-Knorr pyrrole synthesis333

Koch-Haaf carbonylation335

Koenig-Knorr glycosidation337

Kolbe-Schmitt reaction339

Kostanecki reaction341

Kr？hnke pyridine synthesis343

Kumada cross-coupling reaction345

Lawesson's reagent348

Leuckart-Wallach reaction350

Lossen rearrangement352

McFadyen-Stevens reduction354

McMurry coupling356

MacMillan catalyst358

Mannich reaction361

Marshall boronate fragmentation363

Martin's sulfurane dehydrating reagent365

Masamune-Roush conditions367

Meerwein-Ponndorf-Verley reduction369

Meisenheimer complex371

[1,2]-Meisenheimer rearrangement372

[2,3]-Meisenheimer rearrangement374

Meth-Cohn quinoline synthesis376

Meyers oxazoline method378

Meyer-Schuster rearrangement380

Michael addition382

Michaelis-Arbuzov phosphonate synthesis384

Midland reduction386

Mislow-Evans rearrangement388

Mitsunobu reaction390

Miyaura borylation392

Moffatt oxidation394

Montgomery coupling396

Morgan-Walls reaction399

Pictet-Hubert reaction400

Mori-Ban indole synthesis401

Mukaiyama aldol reaction403

Mukaiyama Michael addition405

Mukaiyama reagent406

Myers-Saito cyclization408

Nazarov cyclization410

Neber rearrangement412

Nef reaction414

Negishi cross-coupling reaction416

Nenitzescu indole synthesis418

Nicholas reaction420

Nicolaou dehydrogenation422

Nicolaou hydroxy-dithioketal cyclization424

Nicolaou hydroxy-ketone reductive cyclic ether formation426

Nicolaou oxyselenation428

Noyori asymmetric hydrogenation430

Nozaki-Hiyama-Kishi reaction432

Oppenauer oxidation434

Overman rearrangement436

Paal thiophene synthesis438

Paal-Knorr furan synthesis440

Parham cyclization442

Passerini reaction444

Paternó-Büichi reaction446

Pauson-Khand cyclopentenone synthesis448

Payne rearrangement450

Pechmann coumarin synthesis452

Perkin reaction454

Petasis reaction456

Peterson olefination458

Pictet-Gams isoquinoline synthesis460

Pictet-Spengler tetrahydroisoquinoline synthesis462

Pinacol rearrangement464

Pinner reaction466

Polonovski reaction468

Polonovski-Potier rearrangement470

Pomeranz-Fritsch reaction472

Schlitter-Müller modification473

Prévost trans-dihydroxylation475

Woodward cis-dihydroxylation476

Prins reaction478

Pschorr cyclization480

Pummerer rearrangement483

Ramberg-B？cklund reaction485

Reformatsky reaction487

Regitz diazo synthesis489

Reimer-Tiemann reaction492

Reissert aldehyde synthesis494

Reissert indole synthesis497

Ring-closing metathesis499

Ritter reaction501

Robinson annulation503

Robinson-Gabriel synthesis505

Robinson-Sch？pf reaction507

Rosenmund reduction509

Rubottom oxidation511

Rupe rearrangement513

Saegusa oxidation515

Sakurai allylation reaction518

Sandmeyer reaction520

Schiemann reaction522

Schmidt reaction524

Schmidt's trichloroacetimidate glycosidation reaction526

Shapiro reaction529

Sharpless asymmetric amino hydroxylation531

Sharpless asymmetric epoxidation533

Sharpless asymmetric dihydroxylation536

Sharpless olefin synthesis540

Simmons-Smith reaction543

Skraup quinoline synthesis545

Doebner-von Miller reaction547

Smiles rearrangement549

Newman-Kwart reaction551

Truce-Smile rearrangement553

Sommelet reaction555

Sommelet-Hauser rearrangement557

Sonogashira reaction559

Staudinger ketene cycloaddition561

Staudinger reduction563

Sternbach benzodiazepine synthesis565

Stetter reaction567

Still-Gennari phosphonate reaction569

Stille coupling571

Stille-Kelly reaction573

Stobbe condensation575

Stork enamine reaction577

Strecker amino acid synthesis579

Suzuki coupling581

Swern oxidation583

Takai iodoalkene synthesis585

Tebbe olefination587

Petasis alkenylation587

TEMPO-mediated oxidation589

Thorpe-Ziegler reaction592

Tsuji-Trost allylation594

Ugi reaction596

Ullmann reaction599

van Leusen oxazole synthesis601

Vilsmeier-Haack reaction603

Vilsmeier mechanism for acid chloride formation605

Vinylcyclopropane-cyclopentene rearrangement606

von Braun reaction608

Wacker oxidation610

Wagner-Meerwein rearrangement612

Weiss-Cook reaction614

Wharton oxygen transposition reaction616

Willgerodt-Kindler reaction618

Wittig reaction621

Schlosser modification of the Wittig reaction622

[l,2]-Wittig rearrangement624

[2,3]-Wittig rearrangement626

Wohl-Ziegler reaction628

Wolff rearrangement630

Wolff-Kishner reduction632

Yamaguchi esterification634

Zincke reaction637

Subject Index641